Answer:
Attached below
Explanation:
Free energy of mixing = ÎGmix = Gf - Gi
attached below is the required derivation of the
a) Molar Gibbs energy of mixing
ÎGmix = Gf - Gi
hence : ÎGmix = â©RT ( X1 In X1 + X2 In X2 + X3 In X3 + ------- )
b) molar excess Gibbs energy of mixing
Ni = chemical potential of gas
fi = Fugacity
N°i = Chemical potential of gas when Fugacity = 1
ÎG = RT In ( a2 / a1 ) Â